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Octane Ratings

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Octane is the name of a compound in the alkane series (see Unit 2, Section 1) that has eight carbon atoms (C8H18). Octane is one of many hydrocarbon compounds present in gasoline.

A fuel's octane rating is a measure of its ability to resist catching on fire too soon while it is being compressed and heated in the cylinders of an internal-combustion engine. Octane ratings are sometimes called "anti-knock" ratings, because engines knock loudly when their fuel-air mixtures ignite too early. The higher a fuel's octane number, the more resistant it is to pre-ignition, and the higher the engine's compression ratio can be.

Figure 13. Octane ratings. Propane  and other alternative  fuels have higher octane ratings than gasoline.

Figure 13
Octane ratings
Propane and other alternative fuels have higher octane ratings than gasoline.

Source:  U.S. Department of Energy